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Beilstein J. Org. Chem. 2014, 10, 2649–2653, doi:10.3762/bjoc.10.277
Graphical Abstract
Scheme 1: C-alkynylation of glycals.
Scheme 2: Substrate scope of the reaction process under optimized reaction conditions.
Scheme 3: Plausible mechanism of the Ferrier rearrangement.